Leather – a modern material

It is one of the oldest and yet the most modern natural materials in everyday use. Not least, thanks to modern chemistry, leather is a successful product on a global level that is constantly being reinvented. Above all, however, it is a prime example of sustainability.

Prime example of sustainability

I_1_LederThe Egyptians were already familiar with how to make it, as tomb inscriptions from thousands of years ago show.  The 5,300-year-old iceman known as “Ötzi” was wearing clothing made from several different varieties. Owners of luxury cars swear by it. What’s more, it is impossible to imagine fashion stores without it. Of course, we’re talking about leather. It is one of the oldest, most durable, and still one of the most versatile natural materials in everyday use. Now, thanks to modern chemistry, its best properties can be preserved with an increasing eye to environmental protection and sustainability.


An feat of evolution

These properties are in many respects still unbeatable. Leather is robust and durable. With proper care, leather articles last for decades. There are very few materials that gain charm and attractiveness over time like leather. Leather breathes actively, allowing air and water vapor to circulate – in the clothing industry this is an immensely important advantage over synthetic materials. At the same time, it can be made water-repellent, while, on the other hand, damp leather which has absorbed up to 20 percent water does not feel uncomfortably wet. Leather is elastic, even after years of intense wear. Leather shoes fit to the foot and to a certain extent grow with it. Leather insulates, warms, and yet does not cause us to sweat like many synthetic fibers.

“We mustn’t forget: these properties were developed by the skin over hundreds of thousands of years of evolution,” explains Dietrich Tegtmeyer, Head of the Product Development & Application Division in the Business Unit Leather at LANXESS. “Preserving them is the master art of leather craftsmanship.” Respect for the material and craft resonates throughout the work of Tegtmeyer and his colleagues.


“High-quality leather is leather which makes the most of the original material,” he says. “Unfortunately, a considerable percentage of the leather produced worldwide is low-quality leather which has lost these functional properties.” That is a pity, since leather is one thing above all others: the ultimate recycling product. It is made from animal hides. These are available in any place where meat is produced.  “No bovine dies for its hide,” explains Tegtmeyer. “Hides are an inevitable byproduct and the fact that the leather industry makes a durable, versatile, and highly prized product from them is a prime example of sustainability.”


How leather is made


Making leather from animal hides requires a number of steps. Perhaps the most important of these is tanning. Once the hair, flesh, and uppermost layer of skin have first been removed from the hides, tanning agents are used to ensure that the hide is durable and supple. Tanning agents stabilize the collagen matrix of the skin to prevent the hide from shriveling and hardening as it dries. At the heart of the hide are spiral-shaped protein chains which would normally tighten like rubber bands as the hide dried. Tanning ensures that they stay long and fixed but supple. To a certain extent they act as spacers within the tissue. Only after this step can the hides be passed on for further processing, still moist and uncooled. Hides tanned with chromium have a blue shimmer and are therefore also called “wet blue” at this stage of the process. Similarly, white organically tanned hides are called “wet white.” These pre-tanned hides are the basis for every subsequent form of leather. They get their final color and characteristics during post-tanning, when dyes and oiling agents are also used. The subsequent finishing process deals exclusively with the surface of the leather. This is where the outer layer gets its structure, water-repellent qualities and dirt or UV resistance. This can be achieved using oils or sheer polymer coatings – it all depends on what the customer requires.


Bestseller from Leverkusen

“Leather production is still a real craft, even today,” says Tegtmeyer. “After all, we are dealing with a natural product. As is the case in winegrowing, the raw materials are never completely standardized. It takes a lot of knowhow to ensure that, despite this, a premium product is always produced.” Since the beginnings of the leather industry, which suffered from a bad image for centuries due to the foul-smelling tanneries, a lot has been accomplished. Increasingly refined processes and, above all, synthetic tanning and finishing agents have revolutionized the craft. Chrome tanning deserves special mention, as it is especially effective, inexpensive, and time-efficient. Thus, since its development in the mid-nineteenth century, the use of chromium has become the dominant process worldwide.  Approximately 80 percent of all leathers are made in this way. Chromosal® – a LANXESS bestseller  from Leverkusen – is thus also one of the oldest products made by the specialty chemicals group. It is used to make leathers that will not shrivel even if they are boiled.


However, Chromosal® is only one of about 500 products which LANXESS stocks for leather production.  The Group is not only one of the top 5 manufacturers of leather chemicals worldwide. LANXESS is also one of a very few full-range providers offering and developing appropriate solutions for every step of the leather production process. Even though leather production is a business which is thousands of years old, the potential for innovation is far from exhausted. This is why the Group maintains applied technology facilities not only at its headquarters in Leverkusen but also in all major leather markets worldwide, where leather experts from LANXESS focus on new solutions and products.


Always something new

Leather is a product which is strongly dependent on fashions and trends. Twice a year, designers and producers sketch out the fashion trends for the summer and winter collections 18 months ahead. When it comes to the leather industry, it is the designers in Italy who still set the tone – often in the truest sense of the word. What colors, styles, and finishes will be on catwalks and shelves the season after next depends largely on the ideas of the leather designers.  Thus, LANXESS is once again working this spring with its own designer and a team of leather technicians in Italy on implementing new trends for winter 2015/2016. Leather producers will choose their favorites from these, be it shoes, accessories or car interiors – another growing market.


Sustainable production on the advance


However, the visuals of the end product are not the only decisive factor in this process. Manufacturers are also focusing increasingly on production flows. “Over the past two to three decades, the leather industry has made enormous advances in the areas of resource efficiency and sustainability,” says Tegtmeyer. “Water consumption per square meter of leather has fallen fifty percent. Production-related energy consumption has also halved. Meanwhile, toxic chemicals such as heavy metals have increasingly been banished from processes.” And the development continues. For example, with its new “Sustainable Leather Management” initiative, LANXESS has created a platform which can be used to develop greater gains in efficiency and new processes which go further to protect the environment and save resources. The Leverkusen Group is working with leather producers on questions such as the identification of new enzymes and new-generation raw materials in the leather chemistry. According to Tegtmeyer: “The goal is to use materials with are toxicologically and ecologically safe, further reduce water consumption, and save even more energy. At the same time, leathers need to become even more durable.”


Chemistry decides

What are known as lightweight leathers are another area of development. These are leathers which possess the same properties while weighing in with significantly less weight per square meter. “When we imagine a passenger jet with about 300 seats, lighter seat leathers make a real contribution to the potential for fuel savings,” says Tegtmeyer. “At the same time, leather seats last longer than fabric upholstery, which in turn means less need for replacement.” The same applies in the automobile industry, where the trend is towards ever lighter and more fuel efficient designs. For a provider of solutions such as LANXESS, there is a constant need to win over the customer with innovations. “We are constantly trying out new things in our tanneries,” explains the leather specialist. “We present our best solutions to our customers.” At that point, the leather, costs, and associated material requirements must do the convincing. “About 25 percent of finished leather is modern chemistry. So it is worthwhile for producers to be choosy, since the right chemistry makes an enormous difference,” says Tegtmeyer. “Water, energy, and of course time requirements are variables which any industrial manufacturer must keep in mind, for business reasons alone. Our solutions also need to fit in this respect.”


The world in leather


The global leather market has a volume of about 50 billion euros. Just under two billion square meters of so-called area-measured leather are processed each year – above all for shoes, which still account for over 50 percent of the leather market. Upholsteries, above all car upholsteries, rank second ahead of clothing and specialist applications. Asia, China in particular, has in recent years developed into the largest manufacturer of shoe leathers in the market. A good 50 percent of all leather products now originate in Asia.  Meanwhile, it is Europe which leads in leather chemistry, a global market with a two to three billion euro volume. Thus, the raw material and production chain for leather extend across the entire globe:
•for example, chromium comes from South Africa, the world’s largest chromium producer. LANXESS operates its own mine there.
•The hides come primarily from Brazil or North America, the largest beef producers in the world.
•Europe continues to lead as the trendsetter and leather chemistry provider.
•Most of the processing now takes place in China.
•Leather is purchased and used worldwide.

99 percent utilization

As one of the five top suppliers and one of the few full-range providers, LANXESS is benefiting increasingly from the growing drive for efficiency in the leather market. For example, with its chemicals the Group is making it possible to produce high-quality leathers even from less perfect hides. Thus, a larger portion of each animal hide can be used, which in turns saves resources. Nowadays, around 50 percent of an animal hide is processed into leather. However, other constituents from the hide are being used increasingly, including collagens, proteins, and fats. They can be used for applications such as fertilizers or starting materials in the cosmetics industry. In all, about 99 percent of the animal hide – which is after all a byproduct of our eating habits – can be utilized.

“in my view, this ecological aspect, specifically sensible recycling, is a factor peculiar to the leather market,” explains Tegtmeyer. “An extremely high-quality and durable product which starts life strictly speaking as a byproduct – that is something remarkable.“

The ancient Egyptians and “Ötzi” would have remained unmoved by this. However, for the LANXESS specialty chemicals Group, which is grappling intensively with the environmental consequences of a rapidly growing global population, it is one of the many examples of a philosophy of committed sustainability.